Out of interest, does the main transformer have multiple secondary windings to feed the traction inverters e.g. one per inverter?
The architecture used across the European, Chinese and Japanese electric (or multimode) locomotive OEMs is to have split electrical systems with one DC bus per end / bogie (providing redundancy, there is some cross feed capacity between the two) with 2 or 3 secondary taps feeding each end (providing redundancy, the number depending on total power and optimising transformer cooling rather than being Bo-Bo or Co-Co related), an extra tap for ETS (no redundancy) and the locomotive auxiliary loads being dual fed from both DC buses under normal conditions.
I agree about diesel + ETS being effectively limited to lower ETS loads (in normal usage), but I guess having a high enough output for a full Caley sleeper load might be useful for unplanned diversions etc.
With a full 16 coach sleeper on diesel it would result in Class 25 level traction performance due to ETS loads, probably not good idea. It will more than keep the lights and HVAC on though.
8 coach to Inverness with a 99 should be about 60% of the available traction energy from a pair 73s or 60% more than single 73. The big question is if the timings are relaxed enough north of Dunblane on the diesel section. This will need detailed investigation.
For the shorter Fort William/Aberdeen portions a 99 on diesel would have 45-50% more traction power than 73 and far better adhesion so an obvious swap.
The smaller than 66 fuel tank would might mean a close eye on fuel consumption and careful diagramming is needed.