Caderline, do not telephone. Put it in writing, then you have a copy of whateve ryou sent and thier response. Also, you are likely to speak to a low level member of staff on the phone, and are unlikely to be able to deal with anyoen who is not just using a script.
What you need to do, is to write to someone senior within the organisation. You need to point out that your day out was ruined due to the diffculties you encountered getting home, and that there was no way of you knowing that the train had been cancelled or that a revised timetable had been brought in.
I will happily proof read any letter you wish to send. I used to work as a complaints manager, though not on the railway!
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As you have received £180 of vouchers from East Coast why should you also get a refund of this amount from GC?
The vouchers are compensation for the late running EC service. The OP should not have had to pay for new tickets in the first place. GC should have got them home.
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If there was disruption of some sort then usually they revert to a revised (although not really in printed form) timetable. GC should have made its passengers aware who were booked onto the cancelled service where they should go.
Arriving just before your train departs is never advisable, GC staff would have been somewhere around Kings Cross (EC staff would probably have had little information about what you should do, unless they had been instructed to direct you to an EC service)
How early do you advise arriving at a station before your train is due to depart? Half an hour? An hour?
I don't think it's fair to try and say the passengers arrived too late for their train! They (GC) failed to provide the service, and now they seem to be trying to hide behind the small print.
If this is the way that GC treats its customers, maybe they deserve to go out of business?