This might silence all those who say things like "it's freezing outside the M25" or other things along the lines of how cold the north is compared to the south. On a more serious note though the north is generally has a lower threshold for heat tolerance than the southeast for obvious reasons, I believe the heatwave condition threshold is about 2-3C lower in the north than London, so combining this with them having the highest temperature will be very troubling if this forecast materialises.
The location that sees the hottest temperature appears to be influenced by the wind direction as well urban heat island effects. London obviously has the largest effect, but temperature records have been in places outside London, such as Faversham in 2003 and Cambridge in 2019. It's possible heat was blown out of London to these areas, the latter would be possible on a southerly wind, the former on a westerly wind. Heathrow would certainly see higher temperatures when a E/SE wind blows, and as you say is helped by a load of tarmac and jet engines as well.