A train horn being sounded should not be a 'surprise' to a shunter. You would expect a driver to sound a horn if required at any time. Someone else may have decided to walk across the tracks for example. In my view there would be no case there.
If the working environment allows the shunter to exposed to an unacceptable level of sound because the horn is too loud/the shunter is too close etc, then an employer may be in breach for allowing such a situation to occur if all the procedures were followed correctly by the employees
As others have said, the union lawyer is the person to speak to. IMHO one of the most valuable reasons for being a member.
If the working environment allows the shunter to exposed to an unacceptable level of sound because the horn is too loud/the shunter is too close etc, then an employer may be in breach for allowing such a situation to occur if all the procedures were followed correctly by the employees
As others have said, the union lawyer is the person to speak to. IMHO one of the most valuable reasons for being a member.