The 397s only operate at 110 presently. There is one 802 diagram on the WCML for unit cycling to/from Craigentinny/traction knowledge retention; the 802 does run in electric mode on the WCML.
There's no unit cycling as it's just the one out and back Craigentinny-based diagram. That would have made the whole exercise make a lot more sense but sadly other things intervened...
The reason for the 802 introduction was partly down to the unreliability of the 397s back when the ambition was to run a near-pre-Covid level of service (requiring 10 out of 12 397s in service) and partly down to wanting to retain 802 traction knowledge to allow for diversions along unelectrified lines, e.g. during the Carstairs blockade. Of course, that never came to fruition.
The 397s are still not winning any Golden Spanner awards anytime soon, but the 802 diagram remains as a remnant of previous plans and will probably do so until the next round of cutbacks. It's really sad to think how poor a service is now offered, especially on the popular Liverpool to Glasgow axis, compared to the pre-Covid ambitions.