Breakdown voltage in dry air at sea level is around 30,000 volts per centimetre, which means for 750 volts, the distance would be around a quarter of a millimetre if my sums are right. I have read about London Underground staff wearing 'shunter's shoes' with thick insulating soles and also Tyvek trousers (Tyvek is a non-conducting plastic material that is very difficult to tear or cut). Of course even if you don't touch the rail you could make a short by dropping something metal and the flash would be dangerous. There is a well known fatal case of a staff member in shorts and tee shirt going between wagons and touching the juice rail momentarily with a leg and a wagon buffer with a bare arm. There was, sadly, a probable reason for lack of caution.
Is there any publicly available accident report for this? Curious as to the “reason for lack of caution”.