Below is a brief history of the freight using the line from the late 1980s onwards. Most of the info is taken from
Freight Only Volume 3: Wales and Scotland (Michael Rhodes and Paul Shannon 1988) and
The Last of the Welsh Coal Trains (Chris Davies 2020), plus info from various photo captions.
As already mentioned, Abernant colliery closed in 1988, but the washery remained open until 1992, receiving trainloads of coal from Betws drift mine (on the same branch line, closer to Pantyffynnon). This traffic involved seven return trips per day using class 37s and 18 HAAs. British Coal closed Betws Drift in January 1993. It reopened under private management, from 1994 until final closure in 2003, but I can't find any mention of it despatching traffic by rail during this period.
Gwaun-Cae-Gurwen was an opencast disposal point for coal from East Pit and Garnant. As the coal mined in this part of West Wales was mostly anthracite, the end use was mainly as household coal rather than power station coal. GCG traffic in the late 1980s comprised trainloads of coal in yellow 20ft "Cawoods" containers on PFA wagons to Ellesmere Port for export to Ireland, and also Speedlink coal traffic to various household coal depots in HEA wagons or in 30ft containers on FPA wagons. At this time Pantyffynnon yard was part of the Speedlink coal network, although not for long. Traffic from GCG became more sporadic during the 1990s, and the site closed in 1999. I think some of the final traffic in the late 90s involved trainloads of coal in MEAs for blending at Cwmbargoed, to "sweeten" coal for Aberthaw. GCG and the branch reopened in 2009; footage of the first train is on YouTube titled "Gwaun-Cae- Gurwen. First EWS coal collection Jan 2009." Trainloads of coal in MEAs ran to Onllwyn washery via Swansea Burrows. This traffic lasted until 2019. The final traffic from GCG involved trains of HTA bogie hoppers to CPL at Immingham for production of smokeless fuel briquettes, and to Earles Sidings for Hope Cement works, with the last trains on the branch running in 2020.
Some Flickr links to interesting photos of the branch from the 80s and 90s:
08662 shunts MDOs in the sidings at Betws drift mine in 1983 before a trip to Wernos Washery.
https://www.flickr.com/photos/rivercider/8258498974/
08662 at Pantyffynnon in 1983 with a train of MDOs taking coal from Betws Drift mine to the nearby Wernos Washery. The closure of Wernos in 1988 led to Betws coal being railed to Abernant Washery instead.
https://www.flickr.com/photos/rivercider/9579172076/
A general view of Abernant colliery sidings in 1985
https://www.flickr.com/photos/36034969@N08/49619104236/
The discharge facilty at Abernant Washery in 1988, with 37798 & 37801 unloading HAAs which have originated at Betws Drift Mine
https://www.flickr.com/photos/lickeybanker/31728799176/
08995 trips HAAs from Betws Drift to Pantyfynnon yard in 1991, for onward movement to Abernant behind class 37 traction.
https://www.flickr.com/photos/lickeybanker/10850793084/
08113 shunts HEAs from the loading area to the exchange sidings at GCG in 1990
https://www.flickr.com/photos/lickeybanker/11161654504/
Two views of GCG sidings in 1993 from slightly different angles, with 08598 shunting HEAs (note the internal user wagons, possibly HTVs)
https://www.flickr.com/photos/36034969@N08/53437180312/
https://www.flickr.com/photos/36034969@N08/12858480393/
37701 at GCG exchange sidings in 1994 with HEAs of household coal forming a 6Z46 special to West Drayton
https://www.flickr.com/photos/74165767@N05/50902877196/
37903 at GCG exchange sidings in 1996 with a 6Z29 trial of Cawoods coal containers to Hull Docks
https://www.flickr.com/photos/74165767@N05/51054872621/