As well as S-130 the new S-106. I believe even the standard gauge only 106 subclass are multi-voltage though I could be wrong.
@HS2isgood will be along soon with correct info.
Madrid-Castellon services however were S-100 when they started. Now they could be S-106. The (Vinaros-)Castellon-Madrid-Gijon service clearly is S-130 or S-106.
'AVE International' services also require multi-voltage units, albeit 1500V DC for France.
So it's also a question of what is an 'AVE train'. Not being overly pedantic, but AVE is a marketing name for a service rather than a unit type.
As well as the TGV-base 25kV standard gauge S-100 bought for the original AVE services Renfe also bought TGV-based S-101 3kV broad gauge sets which ran the Valencia-Barcelona fast services, marketed as Euromed. The S-101 were later converted to standard gauge S-100, but some S-100 are multi-voltage for France and some obviously have 3kV for Castellon.
Thanks
Madrid - Castelló standalone services are the only València services from Madrid still ran from Puerta de Atocha (the rest got moved to Chamartín due to terrible capacity management), stop at all high speed stations (just Cuenca and Requena) to València and then Castelló. They're wholly standard gauge, ran by the multisystem (3/25 kV) Class 100.
These are the original AVE from 1992, and a new order is needed soon for a triple purpose: replace the aging 100, revive the French and Eurotunnel ambitions and the new lines to open in the thirties. The 3+2 is regarded as acceptable, the needlessly hard seats to save money are not going to become a permanent fixture, Renfe well knows it was a mistake.
All S-100 are multivoltage, 9 are 3/25/1.5, while the rest are 3/25. The former run Renfe's limited French service, which Renfe hints at withdrawing from 2026, because France won't reduce reliability standards for the 106 like Spain has.
The Gijón - Vinaròs AVE is, as pointed out, a 106. Awful seating for such a long service. It's one of the less reliable services in Spain, a mix of the 106, the multiple engineering minefields on the way, and the double gauge change at València and León, all in a 7-8 hour run.
In Spain AVE services are "any Renfe train on a 300 kph unit", unless they're the low-cost Avlo.
Spain has a haphazard rolling stock policy, multivoltage units are the 100, 106 (all subseries), 107, 120, 121, 130 and 730. All high speed trains, all except the 100 and half the 106 are variable gauge. New electrification in Spain, with a pair of exceptions here and there, is 25 kV, as such the new regional units, classes 460 for Cercanías and 480 for Media Distancia, will be able to use both voltages.
The Ministry of Transport has decided to create a 25 kV rolling stock shortage by sending 24 of the 67 480 purchased, which will start being built soon, to the Catalan subsidiary of Renfe that was created last week and confusingly named Rodalies de Catalunya. Then someone had the amazing idea to make Madrid to Jaén trains faster by using the 200 kph 480 instead of the 160 kph 449, on an all-3 kV line, which barely has any speeds over 160 at all.
Also, the 121's will all be sent to public services, 15 in Avant services near Madrid and 14 to Rodalies, as R16 will need gauge changing at Vila-seca. Obviously, this is Spain, R16 needs 4 diagrams and 14 units will be sent. So they'll spend most of their time in the 140/160 kph max lines where they will be slower than other trains because of their awful door design. So the S-121 commercial service (long-distance) trains will all have to swap for 120.
Lol this is getting rambly.