I can add a few thing to this - even names!
A young "three-loom weaver" suffered a serious accident in 1901, sued the L&YR in 1902, and was awarded £800. Among the named witnesses was John William Hale, foremen porter, who said he had two men under him. One other porter, George Knowles, was named.
In the 1901 census Knowles was a junior porter, aged 20 still living at home in Burnley itself, and his brother at 16 was a "train booking clerk" but we don't know where. I have not found Hale living locally. John W Tate was a station master, and as he lived in the station maser's house at Padiham that was his station. He was 45.
A search of the 1901 census finds 44 men living in Padiham parish with "railway" in their occupation. However, as we have seen, their place of work could have been elsewhere. There are several porters and clerks (mostly very young) and carters. Outside the station itself there are signalmen, a lot of platelayers, and station yard workers (shunters, engine cleaners etc.). There was also a station labourer and a scalesman.
So it isn't possible to identify staff as working at Padiham by where they lived. I also wonder which railway staff came under the stationmaster, directly or via some other manager. I presume signalmen and platelayers didn't, but what about the goods yard and sidings? Of course if anyone, even a driver, stepped onto his station they entered the stationmaster's fief.