It would be very difficult to expand Marylebone in my opinion, both on the approaches to the station (Kilburn to West Hampstead especially) and the station itself. You would have to knock down houses and widen viaducts which pass over busy roads in order to make more space for extra lines into the station. There does appear to be an extra bore in Hampstead Tunnel, and you would still have to go through peoples gardens in order to be able to use that, but the bridge over the WCML immediately outside of Marylebone and St Johns Wood Tunnel can only accommodate two tracks. There is a street immediately to the sidings east of platform 1, so I dont know if there is room for an extra platform there, even if you lose the sidings and the global headquarters of BNP Paribas (the largest bank and one of the ten richest companies in the entire world) shares a wall with Marylebone on the west side of the station. There might be room for an extra platform on that side of the station but again there is residential property immediately beyond the station and as property in NW1 doesnt come cheaply, I doubt any will be purchased in order to be knocked down to make room for more platforms.
IMGhttp://i.imgur.com/7Ji1X.jpg/IMG
You can see that BNP Paribas kills any room for expansion, selling the land to them to build their head office was probably a mistake, but it made somebody a hell of a lot of money at the time.
I believe they were thinking of pulling down the whole station at the time, diverting services into Paddington and Baker Street. Actually, any electrification of the Aylesbury line would make it easier to extend the Metropolitan Line's Amersham service, thus reducing demand on Marylebone, making the former GW route easier to operate.
