I was initially going to make the same point about it being only a penny, but that covers the period they can't charge you for! It seems like there was also some discrepancy on the current bill but it isn't clear what this is (unless what you paid over the errant period is your balance, in which case the discrepancy is around the £1.50 mark)
But I agree, given the extent to which energy (and it's cost) is a big concern for many people, getting an email in your inbox saying "We’re sorry, we underestimated your energy use" is going to cause a lot of panic for many. For something this small, I think it'd have been better placed as a simple "adjustment" on your next bill with accompanying note, but I'm also aware of just how inflexible most energy suppliers are when it comes to documents like that! What's worse is that it's almost probably going to have been an entirely automated issue where a couple of readings went in the wrong order and it got put on this as the closest matching template! Certainly would say you're within your rights to complain to Ovo, they might even fix whatever caused the issue and prevent future recurrences (but I wouldn't hold my breath)