I'd suspect that "375" was chosen as a follow on from "357". Quite why 357 was allocated such I've no idea. It all leaves the 37x range a bit of a mess:
370: APT, the original electric tilting traing
371: the unbuilt "Universal Networker" that was supposed to be built for Thameslink
372: unallocated
373: Eurostar Transmanche Super Train (TMST), TGV based but gauge compatible for UK lines and 3rd rail capable (until they removed the shoes)
374: Eurostar e320, the forthcoming Velaro-D units
375: Southeastern's Electrostar fleet
376: The first "metro" Electrostars, at Southeastern
377: mainly the same thing as 375 (especially since Southeastern changed all their couplers too), at Southern and Thameslink, except the /6 and /7 are significantly updated design but set up to be compatible with the rest of the Southern fleet
378: London Overground "Capitalstar" metro units with wide through gangways and entirely longitudinal seating
379: AC-only new-generation Electrostar (that the 377/6 & /7 are based on) at Greater Anglia, on Stansted and Cambridge services
The other Electorstars:
357: AC only first-generation, C2C
387: Dual voltage 110mph capable that were briefly going to be 377/8 until someone had a weird panic about diagramming.