I would say in locomotives, from a passenger point of view (say a HST vs a 225) there will be more differance from the types of carriages (mk3 or mk4) than from the train at the end (slightly better acceleration from a 91 I would imagine)
However from an MU point of view, EMU's are much better than DMU's Mainly because of a) no engine noise (or significantly less) and b) much less in the way of rattling and vibrations from the seats (once i saw a chapman moving about 2" back and forth from harmonic vibration)
Acceleration is a bit weird. Diesels are capable of giving a certain amount of horsepower and that's it, while tractive effort changes with speed. Electrics have very variable power, but are capable of a virtually-constant tractive effort up to a certain speed, then it drops off, but with variable horsepower. As a result, electrics are excellent for slow-to-medium speed acceleration, while diesels are better with medium-fast, while electrics have better top speeds because of higher top-end power reserves. However, adhesion weight and gear ratio come into it as well.
Therefore, 90 beats HST beats Electra at low speed (high gear ratio on the Electra makes starting sluggish, HST has double the number of driving wheels)
90 beats everything in the 20-60 range, HST and Electra evenly-matched (electric tractive-effort advantage)
90 and Electra about equal in 60-100, HST very close (tractive effort and horsepower about match)
90 "hits the wall" at 110 (gear ratio too low, but I bet they could do 125) HST begins to run out of power above 100 (gravity or light loads can get them above 125 sometimes), Electra just keeps going (more horsepower)
This isn't very exact, but I hope it conveys the general idea.