The 'Standard' Eurostar paths correspond to St Pancras departure times of 01, 04, 31 and 34 minutes past the hour (not all used each hour, of course), based on running non-stop to the tunnel. The 01/31 paths head to Paris, whilst the 04/34 paths head to Brussels. Mirror image in opposite direction. These paths also fit into the LGV Nord standard timetable pattern.
This is partly why on Brussels trains call at Calais and Lille - they can do so, whereas the Paris paths cannot without impeding the Brussels path that follows all the way to Bifurcation de Fretin.
For Eurostars that call at Ebbsfleet or Ashford, they just depart St Pancras slightly earlier than the times above, then pick up the standard timings thereafter. E.g. A Paris train calling at Ebbsfleet becomes xx24 instead of xx31 - 7 extra minutes to allow for the call. It is slightly higher for a call at Ashford due to the slow junctions. This aspect doesn't matter, as there is sufficient gap in Southeastern HS services so that an Ashford caller to Paris can depart St Pancras (say) 5 minutes ahead of an Ebbsfleet caller to Brussels. Having both made their stops (the Ashford call in front taking slightly longer), the Ebbsfleet caller will 'catch up' to be the required 3 minutes behind through the tunnel.
This is why Eurostar departures seem randomly scattered throughout the hour - but there is an underlying standard pattern!