Thank you for the replies posted. My question followed on from the RAIB report (link kindly posted by 'edwin_m' above).
The part of the report that puzzled me was the insinuation that the process for securing vehicles was wrong, given that the method in the instructions to the Shunters working at the location was to apply hand brakes whilst the air brake was still applied. The report states that this is contrary to the industry Rule Book. I have looked this up and it doesn't seem to be the case (although the version of the module concerned that is referenced in the report has been superseded).
If a rake of vehicles was being secured, then releasing the air brake before applying the hand brakes would not be a problem. This could be done one vehicle at a time. Whilst the air brake was being released on a single vehicle, it would be held in place by the others attached to it. Also, if one of the hand brakes had failed on one vehicle in the stabled rake, this would not matter. The risk of vehicles running away is negligible.
But this was a single vehicle stabled on its own. The Shunter cannot be sure whether or not the hand brake had actually applied, regardless of the method used to apply it. I would be interested to know if anybody has experience of this, or if anybody has a view. Would it be standard practice to tell the Shunter to scotch a single vehicle and not rely on the hand brake?
My question about passenger stock has been answered above. Besides, I know that most modern stock is fitted with spring applied parking brakes. These will gradually apply as the air brake leaks off, so presumably this prevents the problem arising.
Overall, my view (having read the report) is that the actions of the Shunter were of little relevance. Given that the report acknowledges that the Shunter cannot be sure that the hand brake has worked, I am not sure what more could be expected. Surely, the primary issue was the failure of the hand brake and the failures in the maintenance regime that should have prevented the failure?
Thanks again for the replies.