Ticket office could do them all in one go, but I wouldn't bother personally unless you're taking the Caledonian Sleeper.
Are you planning to do a first or second class rover?Looking at getting a 7 day All Line Rover.
What is the best way to do reservations as I'm likely to be using Avanti, LNER, GWR, Cross Country, etc... Do I have to contact them all individually ? (I was planning on buying the ticket online). Thanks