There are loads of lines where you can use bi-modes, and as they get electrified you just drop the engines off them!
There's currently loads of lines, however with the potential desire to make rail greener the number of lines is likely to fall over the next 15 years, even then chances are most of those which are left probably wouldn't justify the use of 4 or 5 coach trains which is probably most suited for the WofE line.
80x trains are not suitable for the WoE line - for a start they are the wrong type of electric!
The WofE line is CURRENTLY not suited for 80x trains, that's sure. However long term could be in 20 years time and things could be very different then.
For instance if you are wiring up Reading/Basingstoke and Salisbury/Southampton via Salisbury the Basingstoke isn't the best location to switch electricity sources as it's quite a complex junction.
Likewise any electrification of the North Downs line is likely to cause problems with the interaction between the power sources.
Add in the Southern Approach to Heathrow which may well benefit from running trains which use a single source of electricity, pushing us even further away from the renewal of third rail.
Finally Crossrail 2 is likely to simplify the ability to change from 3rd rail to OHLE further in.
Therefore long term it might be better to run 2 train every other hour from London to (say) Woking using diesel (or even swapping the diesel packs for batteries) before switching to OHLE to Yeovil (or maybe even further out) and then back to diesel/battery to Exeter with the other services to/from Exeter running Exeter, Yeovil, Westbury, Salisbury.