I'm pretty sure all single phase 25kV feeder stations are connected to 132kV or above networks, precisely because the disbalance would be too great for 33kV single phase. The only edge-cases I know of are for really short test track areas in depots like Selhurst and Ashford which run off the 33kV Network Rail system - but it's not like they can power more than one train, very slowly, probably only at night when the draw on the 33kV lines are low. I don't disagree that SFCs can allow way easier DNO connections for AC OLE - but there is basically no such thing as a single phase 33/25kV connection.