The extra pair of tracks from Fenchurch Street station throat to Stepney East were removed again and the alignment handed over to the DLR when that was built in 1987.
The line from Stratford into Fenchurch Street was 1,500V electrified in 1949, then joined at Gas Factory Junction, which is further east from Stepney East, by the Shoeburyness electrification in 1961, and changed to AC. I think some of the overhead structures west of Gas Factory Junction still date from the DC times.
The 6.25kV system was initially quite extensive, the standard class only units, both types on the Shenfield and the Chingford lines, though capable, seem never to have gone beyond into 25kV territory.
Separately, regarding tender locos at Fenchurch Street, I did understand that when at the end Tilbury boat trains were run from there rather than St Pancras, they were handled by 4F 0-6-0s, and later by Brush Type 2 diesels. I think you also got tender locos from the multiple freight depots immediately outside the station, which would come into a platform to take water. There are photos of all of these around.